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Electronegativity Simplified Revision Notes

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Electronegativity

Electronegativity and Prediction of Bond Type

Electronegativity is the measure of an atom's ability to attract the shared pair of electrons in a covalent bond.

Electronegativity values can help determine whether a bond is non-polar covalent, polar covalent, or ionic:

  • If the electronegativity difference is zero, the bond is non-polar covalent (pure covalent), with electrons shared equally between the atoms.
  • If the electronegativity difference is between 0 and 1.7, the bond is polar covalent, where electrons are shared unequally, creating a dipole (e.g., HClHCl).
  • If the electronegativity difference is greater than 1.7, the bond is ionic, where electrons are fully transferred from one atom to another (e.g., NaClNaCl).
infoNote

Example: In HClHCl, chlorine has a higher electronegativity than hydrogen, causing an unequal sharing of electrons, making the bond polar.

Electronegativity Values of the Elements (Pauling Scale)

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