Le Chatelier's Principle (Leaving Cert Chemistry): Flashcards

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Le Chatelier's Principle
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Le Chatelier's Principle

System at equilibrium adjusts to counteract stress

3 stresses affecting equilibrium

Concentration, temperature, pressure

Effect of increasing reactant concentration

Shifts equilibrium towards products

Effect of increasing product concentration

Shifts equilibrium towards reactants

Effect of increasing pressure on gases

Favours side with fewer gas molecules

Effect of decreasing pressure on gases

Favours side with more gas molecules

Effect of increasing temperature

Favours endothermic direction

Effect of decreasing temperature

Favours exothermic direction

Effect of catalysts on equilibrium position

No effect; only increase rate to reach equilibrium

Haber process: pressure used

Around 200 atm

Haber process: temperature used

400-500°C

Haber process: catalyst used

Iron catalyst

Contact process: temperature used

450°C

Contact process: catalyst used

Vanadium oxide (V2O5V_2O_5)

Industrial use of Le Chatelier's Principle

Maximise production of desired products

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