Pyrometallurgy (Leaving Cert Engineering): Flashcards

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Pyrometallurgy
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Pyrometallurgy definition

High-temperature processes to extract metals from ores

Gangue

Unwanted materials separated from metals

Typical pyrometallurgy temp range

500-2000°C

Autogenous process

Process sustained by exothermic reactions alone

Four main pyrometallurgical processes

Calcining, Roasting, Smelting, Refining (CRSR)

Calcining

Thermal decomposition by heating, drives off volatiles

Roasting

Oxidation of metal sulfides at high temps (gas-solid)

Dead roasting

Complete oxidation of sulfide with excess oxygen

Partial roasting

Incomplete oxidation with limited oxygen

Smelting

Reduction of metal oxides using carbon, produces molten metal

Reducing agents in smelting

Coke or charcoal (carbon sources)

Refining in pyrometallurgy

Removes impurities through thermal processes

Metals extracted by pyrometallurgy

Iron, copper, zinc, chromium, tin, manganese

Pyrometallurgy reaction rate advantage

High temps accelerate reactions dramatically

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