Thermoplastic Polymers (Thermoplastics) (Leaving Cert Engineering): Flashcards

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Thermoplastic Polymers (Thermoplastics)
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Key property of thermoplastics

Flexible when heated, rigid when cooled

3 examples of thermoplastics

Acrylic (Perspex), polythene, polypropylene

How thermoplastics are made

Addition polymerisation

Mer definition

Basic unit molecule used in polymerisation

What breaks double bonds in polymerisation

Free radical (catalyst)

Thermoplastic structure type

Amorphous (random, disorganised)

Primary bonding in thermoplastics

Covalent (very strong)

Secondary bonding in thermoplastics

Van Der Wall's Forces (weak)

Why thermoplastics soften when heated

Van Der Wall's Forces break down

Co-polymers purpose

Mix chains to improve properties (harder/softer/rigid/flexible)

Effect of branching

Creates firmer, more rigid material

Effect of crystalline regions

More tensile strength along aligned chains

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