Thermosetting Polymers (Thermosets) (Leaving Cert Engineering): Flashcards

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Thermosetting Polymers (Thermosets)
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Alternative name for thermosetting polymers

Thermosets

Two common examples of thermosets

Bakelite and epoxy resins

Can thermosets be reheated and remoulded once set?

No

Manufacturing process used to produce thermosets

Condensation polymerisation

Small molecule eliminated in condensation polymerisation

Water (extH2extO ext{H}_2 ext{O})

Starting materials for thermosets production

Two distinctly different molecules

Two molecules that react to form Bakelite

Phenol and formaldehyde

Type of structure in thermosets

Cross-linked or networked structure

Type of bonding throughout thermoset structure

Primary bonding

Physical properties of thermosets

Rigid and brittle

Do thermosets have long polymer chains?

No, they have complex cross-linked networks instead

Is thermoset setting reversible or irreversible?

Irreversible

Structure difference: thermosets vs thermoplastics

Cross-linked networks vs long polymer chains

Common early use of Bakelite

Electrical switches and housings

Why are thermosets heat resistant?

Strong primary bonding network maintains shape at high temps

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