Physical Properties, Chain Length, and Branched Groups (Grade 12 NSC Matric Physical Sciences): Flashcards

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Physical Properties, Chain Length, and Branched Groups
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General formula for alkanes

CnH2n+2C_nH_{2n+2} where nn = number of carbon atoms

Van der Waals forces definition

Weak intermolecular attractions between all molecules

Effect of chain length on boiling point

Boiling point increases as chain length increases

Physical state of alkanes with 1-4 carbons at 25°C

Gases

Physical state of alkanes with 17+ carbons at 25°C

Solids

Boiling point: straight-chain vs branched isomers

Straight-chain alkanes have higher boiling points

Why straight-chain alkanes have higher boiling points

Pack closely, more surface area, stronger van der Waals forces

Why branched alkanes have lower boiling points

Branches prevent close packing, reduced surface area contact

Effect of chain length on melting point

Melting point increases as chain length increases

Definition of alkanes

Saturated hydrocarbons with only C and H atoms

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