Melting Point Trend (AQA A-Level Chemistry): Flashcards

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Melting Point Trend
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Structure types with high melting points in Period 3 oxides

Giant ionic or giant covalent structures

Structure of metal oxides in Period 3

Giant ionic

Why MgO\text{MgO} melts higher than Na2O\text{Na}_2\text{O}

Mg2+\text{Mg}^{2+} has higher charge density

Why Al2O3\text{Al}_2\text{O}_3 melts lower than MgO\text{MgO}

Covalent character from Al3+\text{Al}^{3+} polarising O2\text{O}^{2-}

Structure of SiO2\text{SiO}_2

Giant covalent

Why SiO2\text{SiO}_2 has high melting point

Strong covalent bonds throughout 3D lattice

Structure of P4O10\text{P}_4\text{O}_{10} and SO3\text{SO}_3

Simple molecular

Forces in P4O10\text{P}_4\text{O}_{10} and SO3\text{SO}_3

Weak intermolecular forces (van der Waals, dipole-dipole)

Why P4O10\text{P}_4\text{O}_{10} melts higher than SO3\text{SO}_3

Larger size/mass gives stronger van der Waals forces

Why SO3\text{SO}_3 has low melting point

Weak van der Waals forces in small molecular structure

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