Transition Metals (A Level only) (AQA A-Level Chemistry): Flashcards

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Ligand Exchange
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Ligand exchange

When one ligand in a complex ion is replaced by another

Properties altered by ligand exchange

Colour, coordination number, and geometry

Monodentate ligand

Ligand binding through one atom

Bidentate ligand

Ligand binding through two donor atoms

EDTA coordination type

Hexadentate (coordinates through six donor atoms)

Effect of Cl\text{Cl}^- replacing H2O\text{H}_2\text{O}

Coordination number often reduces from 6 to 4

Chelate effect

Increased stability of bi/multidentate ligands compared to monodentate ligands

Entropy change in chelate effect

Increases disorder, favours chelate complex formation

Why is CO toxic in blood?

Binds more strongly than O2\text{O}_2 to Fe(II) in haemoglobin

Colour of [Cu(NH3)4(H2O)2]2+[\text{Cu}(\text{NH}_3)_4(\text{H}_2\text{O})_2]^{2+}

Deep royal blue

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