General Properties of Transition Metals (AQA A-Level Chemistry): Flashcards

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General Properties of Transition Metals
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Definition of transition metals (Ti to Cu)

Form stable ions with incomplete dd-sublevel

What are complex ions?

Central metal ion bonded to ligands via coordinate bonds

Role of ligands in complex formation

Donate lone pairs of electrons to the metal ion

Why transition metals form coloured ions

Electronic transitions in dd-sublevel absorb visible light

Colour of [Cu(H2O)6]2+\text{[Cu(H}_2\text{O})_6]^{2+} complex

Blue

Why variable oxidation states in transition metals?

Close energy levels of 4s4s and 3d3d orbitals

Why transition metals show catalytic activity

Provide lower activation energies, can change oxidation states

Catalyst used in Haber process

Iron (Fe)

Chromium electronic configuration exception

3d54s13d^{5}4s^{1} (half-filled 3d3d provides stability)

Copper electronic configuration exception

3d104s13d^{10}4s^{1} (fully filled 3d3d is more stable)

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