Enthalpy of Solution & Hydration (AQA A-Level Chemistry): Flashcards

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Enthalpy of Solution & Hydration
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Enthalpy of solution definition

Enthalpy change when 1 mol ionic solid dissolves in water (infinitely dilute)

What happens to ionic lattice during dissolution

Breaks down; ions surrounded by solvent molecules

Formula for ΔHsol\Delta H_{sol}

ΔHsol=ΔHlattice+ΔHhydration\Delta H_{sol} = \Delta H_{lattice} + \Delta H_{hydration}

Enthalpy of lattice dissociation definition

Energy to separate 1 mol ionic compound into gaseous ions

Lattice dissociation: endo or exothermic

Endothermic

Enthalpy of hydration definition

Enthalpy change when 1 mol gaseous ions dissolve in water to form hydrated ions

Hydration: endo or exothermic

Exothermic (energy released when water bonds with ions)

Why water dissolves ionic compounds

Water is polar with partial charges on H and O atoms

Which end of water attracts cations (++ ions)

Negative end (oxygen)

Which end of water attracts anions (−- ions)

Positive end (hydrogen)

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