Equilibrium constant (Kp) for Homogeneous Systems (A Level only) (AQA A-Level Chemistry): Flashcards

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Kp Expressions
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KpK_p for gaseous reactions expresses

Equilibrium position in terms of partial pressures

Effect of temperature on KpK_p

Constant at given temperature, changes if temp altered

Definition of mole fraction (xAx_A)

Ratio of moles of A to total moles of all gases

Formula for mole fraction xAx_A

xA=nAnA+nB+nCx_A = \frac{n_A}{n_A + n_B + n_C}

Sum of all mole fractions in a mixture

1

How to calculate partial pressure pAp_A

pA=xA×total pressurep_A = x_A \times \text{total pressure}

General KpK_p expression for aA+bBcC+dDaA + bB \leftrightarrow cC + dD

Kp=(pC)c×(pD)d(pA)a×(pB)bK_p = \frac{(p_C)^c \times (p_D)^d}{(p_A)^a \times (p_B)^b}

Variables pAp_A, pBp_B, etc. in KpK_p represent

Partial pressures of the gases

Exponents in KpK_p expression come from

Coefficients from the balanced equation

Effect of changing overall pressure on KpK_p at constant T

No effect

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