pKa (AQA A-Level Chemistry): Flashcards

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pKa
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Definition of pKapK_a

Logarithmic measure of acid strength derived from KaK_a

Formula: pKapK_a from KaK_a

pKa=log10KapK_a = -\log_{10} K_a

Formula: KaK_a from pKapK_a

Ka=10pKaK_a = 10^{-pK_a}

Weak acid dissociation assumption

[HA]initial[HA]equilibrium[\text{HA}]_{\text{initial}} \approx [\text{HA}]_{\text{equilibrium}}

Formula for [H+][\text{H}^+] from KaK_a

[H+]=Ka×[HA]initial[\text{H}^+] = \sqrt{K_a \times [\text{HA}]_{\text{initial}}}

Formula: pH from [H+][\text{H}^+]

pH=log10[H+]pH = -\log_{10}[\text{H}^+]

pH at half-equivalence point

pH=pKapH = pK_a

Why pH=pKapH = pK_a at half-equiv?

[HA][\text{HA}] and [A][\text{A}^-] concentrations equal

pKapK_a for Ka=1.8×105K_a = 1.8 \times 10^{-5}

4.744.74

Purpose of pKapK_a value

Express small KaK_a values manageably

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