Trends of Period 3 Elements: First Ionisation Energy (AQA A-Level Chemistry): Flashcards

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Trends of Period 3 Elements: First Ionisation Energy
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First ionisation energy definition

Energy to remove 1 mol e−e^- from 1 mol gas atoms to +1+1 ions

1st ionisation energy trend across Period 3

Generally increases from Na to Ar

Nuclear charge across Period 3

Increases (more protons)

Shielding across Period 3

No significant increase (same 3rd shell)

Atomic radius trend across Period 3

Decreases (e−e^- pulled closer to nucleus)

Al ionisation energy anomaly

Outer e−e^- in p sub-shell (higher energy, more shielded)

Outer e−e^- sub-shell: Group 2 vs Group 3

Group 2: s sub-shell; Group 3: p sub-shell

S (group 6) ionisation energy anomaly

p4p^4: 2 e−e^- in same orbital repel, easier to remove

Group 6 e−e^- configuration

p4p^4: two e−e^- paired in same p orbital

Main factors for ionisation energy ↑ in Period 3

↑ nuclear charge, ↓ atomic radius, similar shielding

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