Group 7 (17), the Halogens (AQA A-Level Chemistry): Flashcards

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Physical Properties of Group 7
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Electronegativity definition

Ability of atom to attract bonding pair of electrons in a covalent bond

Electronegativity trend in Group 7

Decreases down the group

Why electronegativity decreases down Group 7

More shells → larger radius → more shielding → less attraction

Boiling point trend in Group 7

Increases down the group

Why boiling points increase down Group 7

Larger molecules → more ee^- → stronger van der Waals forces

Oxidising ability trend in Group 7

Decreases down the group

Strongest oxidising agent in Group 7

Fluorine

Reducing ability trend of halide ions

Increases down the group

Strongest reducing agent among halide ions

Iodide (II^-)

Why halide reducing power increases down group

Larger ions → easier to lose electrons

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