Chemical Properties of Group 7 (AQA A-Level Chemistry): Flashcards

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Chemical Properties of Group 7
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Observation: NaCl + conc. H2SO4H_2SO_4

Misty white fumes (HCl)

Reaction type: NaCl/NaF + H2SO4H_2SO_4

Acid-base (not redox)

Observation: NaBr + H2SO4H_2SO_4 (2nd reaction)

Red-brown Br2Br_2 vapour

Type: NaBr + H2SO4H_2SO_4 (2nd reaction)

Redox reaction

Br oxidation state: NaBr + H2SO4H_2SO_4

−1-1 to 00 (HBr to Br2Br_2)

S oxidation state: NaBr + H2SO4H_2SO_4

+6+6 to +4+4 (H2SO4H_2SO_4 to SO2SO_2)

Purple vapour in NaI + H2SO4H_2SO_4

Iodine (I2I_2) vapour

Yellow solid in NaI + H2SO4H_2SO_4

Sulfur (S)

Rotten egg smell in NaI + H2SO4H_2SO_4

Hydrogen sulfide (H2SH_2S)

Reducing strength: I−I^- vs Br−Br^-

I−I^- much stronger reducing agent

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