Trends in Electronegativity (Leaving Cert Chemistry): Flashcards

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Trends in Electronegativity
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Definition of electronegativity

Relative attraction of atom for shared pair of electrons in covalent bond

Electronegativity trend down groups

Decreases

Electronegativity trend across periods

Increases

Why electronegativity decreases down groups (atomic size)

Larger atomic radius; electrons further from nucleus

Why electronegativity decreases down groups (screening)

Inner shells shield outer electrons from nucleus

Why electronegativity increases across periods (charge)

More protons increase effective nuclear charge

Why electronegativity increases across periods (size)

Smaller atomic radius; electrons closer to nucleus

Element with highest electronegativity

Fluorine

Electronegativity value of fluorine

4.0

Electronegativity value of chlorine

3.0

Location of highest electronegativity on periodic table

Top-right corner

Location of lowest electronegativity on periodic table

Bottom-left corner

What electronegativity helps predict

Bond polarity, ionic vs covalent compounds, chemical behaviour

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