Common Ion Effect (HSC SSCE Chemistry): Flashcards

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Common Ion Effect
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Common ion effect definition

Adding common ion decreases solubility of sparingly soluble salt

Common ion

Ion shared between two substances in solution

Effect of adding common ion on solubility

Decreases the solubility of the salt

Reason for common ion effect

Le Chatelier's principle - equilibrium shifts to reduce added ion

Equilibrium shift direction with common ion

Backwards (left), favouring reverse reaction

General form of KspK_{sp} expression

Product of ion concentrations raised to stoichiometric powers

Simplifying assumption: common ion calculations

If scs \ll c, then (c+s)c(c + s) \approx c

Effect on precipitation when common ion added

More solid precipitates out of solution

Condition for precipitate formation

Qsp>KspQ_{sp} > K_{sp}

AgI solubility: 0.250 M KI vs water

27 million times less soluble in KI

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