Electricity From Redox Reactions (HSC SSCE Chemistry): Flashcards

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Electricity From Redox Reactions
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Electrochemistry definition

Study of connections between chemistry and electricity

How batteries generate electricity

Through chemical reactions

Electric current definition

Flow of electrons through a conductor

Key principle for redox reactions to produce electricity

Oxidation & reduction at separate locations, e⁻ via wire

Voltage of copper-silver cell

Approximately 0.5 V

Electron flow direction in Cu-Ag cell

From copper through external circuit to silver wire

Oxidation reaction at copper electrode

Cu(s)Cu2+(aq)+2e\text{Cu(s)} \rightarrow \text{Cu}^{2+}\text{(aq)} + 2e^-

Reduction reaction at silver electrode

Ag+(aq)+eAg(s)\text{Ag}^+\text{(aq)} + e^- \rightarrow \text{Ag(s)}

Overall reaction in Cu-Ag cell

Cu+2Ag+Cu2++2Ag\text{Cu} + 2\text{Ag}^+ \rightarrow \text{Cu}^{2+} + 2\text{Ag}

Galvanic cell definition

Generates electricity from spontaneous redox reactions

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