Dissociation Constants for Acids (HSC SSCE Chemistry): Quizzes

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Dissociation Constants for Acids
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What does the acid dissociation constant (KaK_a) quantify for a weak acid?

The extent of ionisation in water

Why is water not included in the KaK_a expression for weak acids?

Water is the solvent; its conc. is constant

What does a KaK_a value much less than 1 indicate about an acid?

It ionises only to a small extent

Which acid is the strongest weak acid according to the KaK_a table?

Hydrofluoric acid (7.6×1047.6 \times 10^{-4})

What assumption is made about [HA] when calculating KaK_a for weak acids?

[HA]equilibrium ≈ [HA]initial

In the simplified KaK_a formula, why does Ka=[H3O+]2[HA]K_a = \frac{[\text{H}_3\text{O}^+]^2}{[\text{HA}]}?

Because [A⁻] = [H₃O⁺]

What formula calculates the percentage ionisation of a weak acid?

[A][HA]initial×100%\frac{[\text{A}^-]}{[\text{HA}]_{initial}} \times 100\%

For polyprotic acids, how do the KaK_a values compare?

Ka1>Ka2>Ka3K_{a1} > K_{a2} > K_{a3}

How does pKaK_a relate to acid strength?

Smaller pKaK_a means stronger acid

For H₂SO₄, what type of acid behaviour does the second ionisation step show?

Weak acid (Ka2=102K_{a2} = 10^{-2})

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