Making Buffers (AQA A-Level Chemistry): Flashcards

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Making Buffers
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Function of buffer solutions

Resist pH changes when small amounts of acid/base added

Components of a buffer

Weak acid + conjugate base OR weak base + conjugate acid

Henderson-Hasselbalch equation

pH=pKa+log([salt][acid])pH = pK_a + \log(\frac{[\text{salt}]}{[\text{acid}]})

pKapK_a of ethanoic acid

4.75

pH of 1:1 ethanoic acid:ethanoate buffer

4.75

Mass of CH3COONaCH_3COONa in direct method

2.05 g

Volumes in indirect method

25 cm³ NaOH + 50 cm³ ethanoic acid

Final volume in volumetric flask

250 cm³

Salt:acid ratio for pH 4.25

0.5:1

Volume & concentration to test buffer

1 cm³ of 1.0 mol dm⁻³ to 100 cm³ buffer

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