Group 1 (AQA GCSE Chemistry Combined Science): Revision Notes
Group 1
Group 1 elements are known as alkali metals. These are reactive metals that share similar properties and show clear patterns as you move down the group.
Properties of alkali metals
Alkali metals share several key characteristics that make them unique among the elements:
Physical properties:
- They are metals with a shiny appearance
- Low density - the first three elements (lithium, sodium, potassium) are less dense than water, so they float
- Melting and boiling points decrease as you go down the group
Chemical properties:
- Form ions with a +1 charge when they react
- React vigorously with water to produce hydroxides and hydrogen gas
- React with oxygen to form white, solid ionic oxides
- React with chlorine to form white, solid, soluble ionic chlorides
The consistent formation of +1 ions across all Group 1 elements is due to their similar electron configuration - they all have exactly one electron in their outermost shell that they readily lose during chemical reactions.
The reactivity pattern
Understanding the reactivity pattern is crucial for predicting how Group 1 elements will behave in chemical reactions.
Reactivity increases as you go down Group 1. This means:
- Lithium is the least reactive
- Francium is the most reactive
Why does this happen?
All Group 1 elements have one electron in their outer shell. This outer electron is easily lost during reactions, forming a +1 ion.
As you move down the group:
- The outer electron gets further away from the nucleus
- This makes it easier to lose the outer electron
- Therefore, the elements become more reactive
Reactions with water
All alkali metals react with water following the same general pattern, but with increasing vigour as you go down the group.
General equation:
Worked Example: Sodium reacting with water
Word equation: sodium + water → sodium hydroxide + hydrogen
Balanced chemical equation:
What you observe:
- The metal moves around on the water surface
- Hydrogen gas is produced (you can see bubbles)
- The solution becomes alkaline due to the hydroxide formed
- More reactive metals (like potassium) react more vigorously
Examples of reactions
Chemical Reactions of Alkali Metals
With chlorine:
- Word equation: Sodium + chlorine → sodium chloride
- Chemical equation:
With water (other examples):
- Potassium reacts very quickly and may catch fire
- Rubidium reacts even more violently
- When ionic products dissolve in water, they form colourless solutions
Key Patterns to Remember
Going down Group 1:
- Elements become more reactive
- Melting points decrease
- Boiling points decrease
- Reactions with water become more vigorous
All Group 1 elements:
- Have one outer electron
- Form +1 ions
- React in similar ways but with different intensities
Essential Points About Group 1 Elements:
- Group 1 elements are called alkali metals
- They all have one electron in their outer shell, making them reactive
- Reactivity increases going down the group because the outer electron is further from the nucleus
- They react with water to make hydroxides and hydrogen gas
- The first three elements float on water because they have low density