Alkenes (AQA GCSE Chemistry Combined Science): Revision Notes
Alkenes
What are alkenes?
Alkenes are a type of hydrocarbon. This means they contain only hydrogen and carbon atoms. The key feature of alkenes is that they have a carbon-to-carbon double bond ().
Alkenes are made by cracking long-chain alkanes. Cracking is a process that breaks down larger molecules into smaller, more useful ones.
The double bond in alkenes is what makes them different from alkanes, which only have single bonds between carbon atoms.
Key properties of alkenes
Alkenes are unsaturated compounds. This means they have fewer hydrogen atoms than they could possibly have because of the double bond. The double bond takes up space that could have been filled by hydrogen atoms.
General formula:
Understanding the General Formula
The formula means that for every carbon atoms, there are hydrogen atoms. This is always two fewer hydrogen atoms than the equivalent alkane ().
For example:
- Ethene:
- Propene:
The bromine water test
This is a simple test to tell the difference between alkanes and alkenes.
How to do the test:
- Shake the substance with bromine water (an orange solution)
- Watch what happens to the colour
Results:
- If it's an alkene: The mixture turns from orange to colourless
- If it's an alkane: The mixture stays orange (no change)
This test works because alkenes react with bromine water through an addition reaction, but alkanes do not react under normal conditions. The bromine atoms add across the double bond, causing the orange colour to disappear.
Why are alkenes more reactive than alkanes?
Alkenes are more reactive than alkanes because of their double bond. The double bond can break easily, allowing alkenes to react with other substances.
Key difference:
- Alkenes: Have a double bond → more reactive
- Alkanes: Have only single bonds → less reactive
The double bond is a region of high electron density, making it attractive to other chemicals that want to react with electrons.
Identifying alkenes in molecules
To spot an alkene molecule, look for:
- Only carbon and hydrogen atoms (hydrocarbon)
- At least one double bond
- Fewer hydrogen atoms than the equivalent alkane
Key Points to Remember:
- Alkenes are hydrocarbons with a double bond
- The general formula is
- They are unsaturated compounds
- Bromine water turns from orange to colourless with alkenes
- Alkenes are more reactive than alkanes because of the double bond