Required Practical: Electrolysis of Aqueous Solutions (OCR GCSE Chemistry A, Combined (Gateway Science Suite)): Flashcards

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Required Practical: Electrolysis of Aqueous Solutions
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Why is aqueous electrolysis more complex?

Water produces H+H^+ & OHOH^- ions that can react

Water dissociation products in electrolysis

H+H^+ and OHOH^- ions

Cathode rule: which ion is reduced?

The less reactive ion

Anode rule: which ion is oxidised?

The ion that oxidises more easily

CuSO4CuSO_4 electrolysis: cathode ion reduced

Cu2+Cu^{2+} (Cu less reactive than H)

CuSO4CuSO_4 electrolysis: cathode product

Solid copper deposits

CuSO4CuSO_4 electrolysis: anode ion oxidised

OHOH^- (no halide ions present)

CuSO4CuSO_4 electrolysis: anode products

Oxygen gas and water

NaCl electrolysis: cathode ion reduced

H+H^+ (Na more reactive than H)

NaCl electrolysis: cathode product

Hydrogen gas

NaCl electrolysis: anode ion oxidised

ClCl^- (chloride is a halide ion)

NaCl electrolysis: anode product

Chlorine gas

Anode: ion oxidised when no halides

OHOH^- ions, producing oxygen gas

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