Electronegativity and the Continuum of Chemical Bonding (LC 2027) (Leaving Cert Chemistry): Flashcards

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Electronegativity
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Electronegativity definition

Relative attraction of atom for shared ee^- in covalent bond

Who developed electronegativity scale in 1930s?

Linus Pauling

Highest electronegativity value and element

Fluorine: 3.98

Meaning of δ\delta (delta) symbol in bonding

Partial charge

When does pure covalent bonding occur?

Identical atoms or electronegativity difference 0\approx 0

Characteristic of polar covalent bonds

Unequal ee^- sharing; one end δ+\delta^+, other end δ\delta^-

Electronegativity difference 0-0.5 gives what bond?

Pure covalent (negligible polarity)

Electronegativity difference 0.5-1.7 gives what bond?

Polar covalent

Electronegativity difference >1.7>1.7 gives what bonding?

Ionic bonding

Two conditions for a molecule to be polar

Polar covalent bonds + asymmetrical shape

Why is H2OH_2O polar overall?

Has polar bonds and is V-shaped (asymmetrical)

Charged rod near polar liquid stream does what?

Stream bends towards rod

How do microwaves cook food using polarity?

Polar H2OH_2O molecules rotate, creating friction and heat

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