Intermolecular Forces (Leaving Cert Chemistry): Flashcards

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Intermolecular Forces
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Intramolecular bonding

Bonding within a molecule (e.g., covalent bonds)

Intermolecular forces

Forces of attraction between separate molecules

Van der Waals forces

Weak intermolecular forces that exist between all molecules

Discoverer of van der Waals forces

Johannes van der Waals (Dutch scientist)

How strong are van der Waals forces vs. covalent/ionic bonds?

Van der Waals are much weaker

Molecules with van der Waals forces

All molecules (polar & non-polar)

Physical properties affected by van der Waals

Boiling points, melting points, solubility

How does distance affect van der Waals forces?

Strength decreases greatly as distance increases

London dispersion forces characteristics

Weakest type; present between all molecules

Cause of London dispersion forces

Temporary fluctuations in electron distribution

Hydrogen bonding occurrence

H bonded to O, N, or F

Ion-dipole forces occurrence

Between ions and polar molecules

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