Self-Ionisation of Water (Leaving Cert Chemistry): Quizzes

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Self-Ionisation of Water
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What is self-ionisation of water?

Water molecules spontaneously form ions

What ions are produced during self-ionisation of water?

H+\text{H}^+ and OH−\text{OH}^-

What is the value of KwK_w at 25°C?

1.0×10−141.0 \times 10^{-14}

What is the expression for KwK_w?

Kw=[H+][OH−]K_w = [\text{H}^+][\text{OH}^-]

What is [H+][\text{H}^+] in pure water at 25°C?

1.0×10−71.0 \times 10^{-7} M

How does temperature affect KwK_w?

KwK_w increases as temperature rises

What is the enthalpy change for self-ionisation of water?

ΔH=+55.8\Delta H = +55.8 kJ mol−1^{-1}

In which direction does the equilibrium of water self-ionisation lie?

Heavily towards the left

In an acidic solution at 25°C, what is true about [H+][\text{H}^+]?

[H+]>1.0×10−7[\text{H}^+] > 1.0 \times 10^{-7} M

In a basic solution at 25°C, what is true about [OH−][\text{OH}^-]?

[OH−]>1.0×10−7[\text{OH}^-] > 1.0 \times 10^{-7} M

What happens when [H+][\text{H}^+] increases in aqueous solution at constant temperature?

[OH−][\text{OH}^-] decreases to maintain KwK_w

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