Substitution Reactions (Leaving Cert Chemistry): Quizzes

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Substitution Reactions
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What is a substitution reaction?

An atom/group replaced by another

Why do alkanes typically undergo substitution reactions?

Strong bonds & no reactive functional groups

What is a free radical?

Atom/group with unpaired electron

How are free radicals represented in chemical equations?

With a dot (•) next to the symbol

What is required to initiate free radical substitution?

UV light or heat

What is homolytic fission?

Bond breaks, each atom gets one electron

What happens in the initiation step with Cl2\text{Cl}_2?

UV light produces 2Cl∙2\text{Cl}^\bullet

In propagation step 2, what does Cl∙+CH4\text{Cl}^\bullet + \text{CH}_4 produce?

HCl+CH3∙\text{HCl} + \text{CH}_3^\bullet

What does CH3∙+Cl2\text{CH}_3^\bullet + \text{Cl}_2 produce in propagation step 3?

CH3Cl+Cl∙\text{CH}_3\text{Cl} + \text{Cl}^\bullet

Why is free radical substitution called a chain reaction?

Step 3 regenerates Cl∙\text{Cl}^\bullet for step 2

What happens when two CH3∙\text{CH}_3^\bullet radicals combine in termination?

Form ethane (C2H6\text{C}_2\text{H}_6)

Why does ethane formation support the free radical mechanism?

Only explained by CH3∙\text{CH}_3^\bullet combining

What evidence shows the reaction needs UV light?

Reaction only occurs with UV exposure

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