NMR Spectroscopy (HSC SSCE Chemistry): Flashcards

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NMR Spectroscopy
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NMR spectroscopy purpose

Determine structures of organic molecules

Nuclei requirement for NMR

Odd number of nucleons

TMS chemical shift value

0 ppm

Chemical shift symbol & units

δ\delta, measured in ppm

n + 1 rule

Peaks = neighbouring protons + 1

Why deuterated solvents used

2^2H has even nucleons, invisible to NMR

Triplet peak ratio

1:2:1

OH proton behaviour in NMR

Always singlet, doesn't split

13^{13}C NMR splitting

No splitting observed

Shielding in NMR

Electrons shield nucleus from magnetic field

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