Standard Enthalpy of Formation (HSC SSCE Chemistry): Flashcards

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Standard Enthalpy of Formation
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Standard state pressure for thermodynamic measurements

100.0extkPa100.0 ext{ kPa}

Standard state concentration for solutes in solution

1extmolL11 ext{ mol L}^{-1}

Standard enthalpy of formation (DeltaHf°Delta H_f°)

Enthalpy change forming 1 mole from elements in std states

Moles of compound in standard formation equations

Always exactly one mole

DeltaHf°Delta H_f° for elements in their standard state

Zero (0)

Symbol indicating standard conditions in enthalpy

°° (superscript degree symbol)

Formula: DeltaH°Delta H° from formation enthalpies

sumDeltaHf°sum Delta H_f°(products) sumDeltaHf°- sum Delta H_f°(reactants)

DeltaHf°Delta H_f° of H₂O(l) at 298 K in kJ·mol⁻¹

285-285

Reason for fractional coefficients in formation eqns

To form exactly one mole of the compound

Importance of physical state for DeltaHf°Delta H_f° values

Same compound has different DeltaHf°Delta H_f° in different states

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