Alcohols (HSC SSCE Chemistry): Flashcards

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Oxidation
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First product when primary alcohols are oxidised

Aldehydes

Product when aldehydes are oxidised further

Carboxylic acids

Product when secondary alcohols are oxidised

Ketones

Can tertiary alcohols be oxidised under normal conditions?

No

Why tertiary alcohols resist oxidation

No H atoms on C bearing -OH; would need to break C-C bonds

Two common oxidising agents for alcohols

Acidified MnO4\text{MnO}_4^- and acidified Cr2O72\text{Cr}_2\text{O}_7^{2-}

Dichromate colour change when oxidation occurs

Orange to green

Dichromate colour with tertiary alcohols

Remains orange (no colour change)

Technique to collect aldehydes from primary alcohol oxidation

Distillation

Can ketones be oxidised further under normal conditions?

No

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