Polymers (HSC SSCE Chemistry): Flashcards

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Synthetic Polymers
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Monomers

Small building-block molecules that link to form polymers

Polymerisation

Chemical process connecting monomers into long chains

Thermoplastic polymers when heated

Soften and can be melted/remoulded; recyclable

Thermosetting polymers when heated

Don't soften; cross-linked structure prevents remoulding

Examples of thermoplastic polymers

Polyethylene, PVC, PET

Examples of thermosetting polymers

Polyurethane, melamine, Bakelite

Most widely used monomer for synthetic polymers

Ethylene (ethene), formula C2H4\text{C}_2\text{H}_4

Catalytic cracking conditions

~500°C, 4-20 atm, zeolite catalysts

Thermal cracking conditions

~700°C, up to 70 atm, no catalyst

Two major challenges with synthetic polymers

Environmental persistence & crude oil dependency

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