Temperature and Activation Energy (HSC SSCE Chemistry): Flashcards

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Temperature and Activation Energy
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Definition of activation energy (EaE_a)

Min. energy barrier reactants must overcome to form products

Symbol for activation energy

EaE_a

How activation energy is determined

Experimentally by measuring reaction rates at various temps

Effect of larger EaE_a on temperature sensitivity

Stronger response to temperature increases

What activation energy represents physically

Energy hill/barrier particles must climb to react

Result when particles collide with sufficient energy

Overcome barrier, transform into products

Result when particles lack sufficient energy

Bounce apart, remain as unreacted reactants

Effect of higher EaE_a on reaction rate

Slower reaction (fewer collisions have sufficient energy)

Why higher temperature speeds up reactions

More particles have energy to overcome EaE_a barrier

Two conditions for successful collision (collision theory)

Sufficient energy (exceeding EaE_a) + correct orientation

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