Quantitative Analysis of Ions (HSC SSCE Chemistry): Quizzes

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Quantitative Analysis of Ions
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What are the two main approaches for quantitative ion analysis?

Precipitation titrations & gravimetric

What indicator is used in Mohr's method?

Chromate ions forming red-brown Ag2CrO4\text{Ag}_2\text{CrO}_4

Why must pH be 6-9 in Mohr's method?

Higher pH precipitates AgOH; lower pH protonates chromate

Why is a blank titration needed in Mohr's method?

End point detected past equivalence point

What type of titration is Volhard's method?

Back titration with excess Ag+\text{Ag}^+

In Volhard's method, when must precipitate be filtered before titration?

When KspK_{sp} of precipitate > KspK_{sp} of AgSCN

What color signals the end point in Volhard's method?

Blood-red Fe(SCN)2+\text{Fe(SCN)}^{2+} complex

How do absorption indicators work in Fajan's method?

They adsorb onto precipitate surface

Which is a major error source in gravimetric analysis?

Water remaining in the precipitate

What measurements does gravimetric analysis primarily use?

Mass of dried precipitate

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