Quantitative Analysis of Ions (HSC SSCE Chemistry): Flashcards

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Quantitative Analysis of Ions
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Two main approaches for quantitative ion analysis

Precipitation titrations and gravimetric analysis

What precipitation titrations determine

Ion concentrations using precipitation reactions

Mohr's method indicator

Chromate ions (CrO42\text{CrO}_4^{2-})

pH range required for Mohr's method

pH 6-9

Volhard's method titration type

Back titration in acidic solution

Volhard's indicator & end point colour

Fe3+\text{Fe}^{3+} ions, blood-red Fe(SCN)2+\text{Fe(SCN)}^{2+} complex

How Fajan's method indicators work

Adsorb onto precipitate surface and change colour

Gravimetric analysis measurement type

Mass measurements of precipitates

Major error sources in gravimetric analysis

Contamination, loss, incomplete pptn, retained water

Technique for complete drying in gravimetric analysis

Dry to constant mass (repeat until no change)

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