Structural Isomerism (AQA A-Level Chemistry): Flashcards

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Structural Isomerism
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What are isomers?

Molecules with same molecular formula, different arrangements

Structural isomerism

Atoms connected in different ways

3 types of structural isomerism?

Chain, position, functional group

Chain isomerism

C atoms arranged differently, different C skeletons

Branched chain isomers boiling point

Lower BP, weaker van der Waals forces

Position isomerism

Functional group at different positions on C chain

Position isomers properties

Similar physical, slightly different chemical properties

Functional group isomerism

Same molecular formula, different functional groups

Functional group isomers properties

Completely different chemical and physical properties

C2H6OC_2H_6O functional group isomers

Ethanol (−OH-OH) and dimethyl ether (C−O−CC-O-C)

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