Elimination Reactions of Alcohols (AQA A-Level Chemistry): Flashcards

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Elimination Reactions of Alcohols
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Elimination reaction

Removal of small molecule, forming double bond

Molecule removed in alcohol dehydration

Water (H2OH_2O)

Temp. for ethanol dehydration

170°C

Acid catalysts for alcohol dehydration

Conc. H2SO4H_2SO_4 or H3PO4H_3PO_4

Product of ethanol dehydration

Ethene

1st step: dehydration mechanism

Protonation of -OH by acid (makes better leaving group)

2nd step: dehydration mechanism

Water leaves, carbocation forms

3rd step: dehydration mechanism

H removed from adjacent carbon, double bond forms

Products from unsymmetrical alcohols

Multiple products (double bond in different positions)

Use of alkenes from alcohol dehydration

Addition polymers (sustainable alternative to crude oil)

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