Elimination and Redox Reactions (Leaving Cert Chemistry): Flashcards

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Elimination and Redox Reactions
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Elimination reaction

Small molecule removed, double bond created

Most common elimination type

Dehydration (removal of H2OH_2O)

Catalyst for alcohol dehydration

Aluminium oxide (Al2O3Al_2O_3) with heat

Product of ethanol dehydration

Ethene

Removed in alcohol dehydration

-OH group and H from adjacent C as H2OH_2O

Oxidation in organic chemistry

Adding oxygen or removing hydrogen

Reduction in organic chemistry

Adding hydrogen or removing oxygen

Primary alcohol oxidation sequence

Aldehyde, then carboxylic acid

Secondary alcohol oxidation product

Ketone

Tertiary alcohol oxidation

Cannot be easily oxidised

Aldehyde reduction product

Primary alcohol

Ketone reduction product

Secondary alcohol

Oxidising agent for alcohols

Potassium permanganate (KMnO4KMnO_4) in acid

Reducing agent for carbonyls

Hydrogen gas (H2H_2) with nickel catalyst

Carboxylic acid reduction product

Primary alcohol (via aldehyde)

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