Galvanic (Voltaic) Cells (Leaving Cert Chemistry): Flashcards

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Galvanic (Voltaic) Cells
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Energy conversion in galvanic cells

Chemical energy to electrical energy

Alternative name for a galvanic cell

Voltaic cell

Definition of electrode in galvanic cell

Solid conductor that carries electricity

Definition of electrolyte

Solution containing ions that conducts electricity

Definition of half-cell

Electrode in solution of its own ions; site of oxidation or reduction

Process at anode

Oxidation

Process at cathode

Reduction

Charge of anode

Negative

Charge of cathode

Positive

Main function of salt bridge

Maintains electrical neutrality and allows ion flow

Direction of electron flow in external circuit

From anode to cathode

Voltage of Zn-Cu galvanic cell

Approximately 1.1 volts

Oxidation half-equation at Zn electrode

Zn→Zn2++2e−\text{Zn} \rightarrow \text{Zn}^{2+} + 2e^-

Reduction half-equation at Cu electrode

Cu2++2e−→Cu\text{Cu}^{2+} + 2e^- \rightarrow \text{Cu}

Overall cell reaction for Zn-Cu cell

Zn+Cu2+→Zn2++Cu\text{Zn} + \text{Cu}^{2+} \rightarrow \text{Zn}^{2+} + \text{Cu}

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