The Electrochemical Series (Leaving Cert Chemistry): Flashcards

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The Electrochemical Series
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What does the electrochemical series rank?

Elements by their tendency to lose electrons

Order of elements in electrochemical series

Most reactive at top, least reactive at bottom

Reference point for electrochemical series

Hydrogen half-cell

Standard electrode potential of hydrogen

0.00 volts

Most reactive metals in series

K, Na, Ca, Mg, Al

Least reactive metals in series

Cu, Hg, Ag, Au

Tendency of metals at top of series

Greater tendency to lose outer electrons

Displacement reaction rule

More reactive metal displaces less reactive metal

Products when Mg displaces Cu2+\text{Cu}^{2+}

Mg2++Cu\text{Mg}^{2+} + \text{Cu}

What is galvanising?

Coating iron/steel with zinc

Why does galvanising protect iron?

Zn is higher in series, corrodes preferentially

Cathodic protection method

Attach more reactive metal (sacrificial anode) to steel

Industrial use: scrap iron in copper sulfate

Iron displaces copper from solution

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