Addition Reactions (Leaving Cert Chemistry): Quizzes

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Addition Reactions
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What is the key feature of addition reactions?

Atoms added across double bond

Which type of organic compound is particularly important for addition reactions?

Alkenes

What happens to a halogen molecule when it approaches an alkene?

It becomes polarised

What acts as a nucleophile in the first step of halogen addition?

ππ electrons in C=C

What type of fission occurs when the halogen molecule breaks during addition?

Heterolytic fission

Which intermediate is more likely in symmetrical alkene addition?

Cyclic chloronium ion

What is the main product when ethene reacts with Cl2\text{Cl}_2?

1,2-dichloroethane

What side product forms when ethene reacts with Cl2\text{Cl}_2 in water?

2-chloroethanol

What is the reactivity order for hydrogen halides adding to alkenes?

HI > HBr > HCl > HF

Why does HI react fastest with alkenes?

Weakest H-X bond

What is the bond enthalpy of HF?

567 kJ mol−1^{-1}

Which factor increases the rate of initial electrophilic attack?

Greater bond polarity

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