Addition Reactions (Leaving Cert Chemistry): Flashcards

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Addition Reactions
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What are addition reactions?

Two molecules combine across a double bond

What do addition reactions add across?

Double bonds (C=C)

Product type when halogens add to alkenes

Dihalogenated products

What happens to halogen approaching alkene?

Becomes polarised (δ+\delta^+ and δ−\delta^-)

Role of π\pi electrons in addition mechanism

Act as nucleophile, attack positive halogen

Type of fission when Cl-Cl bond breaks

Heterolytic fission

Two possible intermediates in halogen addition

Carbocation or cyclic chloronium ion

More likely intermediate with ethene

Cyclic chloronium ion

Product of ethene + Cl2\text{Cl}_2

1,2-dichloroethane

Side product when water present with Cl2\text{Cl}_2 addition

2-chloroethanol

Reactivity order: hydrogen halides with alkenes

HI > HBr > HCl > HF

Why does HI react fastest with alkenes?

Weakest H-X bond, easiest to break

Are atoms removed in addition reactions?

No, all atoms add on

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