Addition Reactions (Leaving Cert Chemistry): Flashcards
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13 cards from this deck
What are addition reactions?
What are addition reactions?
Two molecules combine across a double bond
What do addition reactions add across?
What do addition reactions add across?
Double bonds (C=C)
Product type when halogens add to alkenes
Product type when halogens add to alkenes
Dihalogenated products
What happens to halogen approaching alkene?
What happens to halogen approaching alkene?
Becomes polarised ( and )
Role of electrons in addition mechanism
Role of electrons in addition mechanism
Act as nucleophile, attack positive halogen
Type of fission when Cl-Cl bond breaks
Type of fission when Cl-Cl bond breaks
Heterolytic fission
Two possible intermediates in halogen addition
Two possible intermediates in halogen addition
Carbocation or cyclic chloronium ion
More likely intermediate with ethene
More likely intermediate with ethene
Cyclic chloronium ion
Product of ethene +
Product of ethene +
1,2-dichloroethane
Side product when water present with addition
Side product when water present with addition
2-chloroethanol
Reactivity order: hydrogen halides with alkenes
Reactivity order: hydrogen halides with alkenes
HI > HBr > HCl > HF
Why does HI react fastest with alkenes?
Why does HI react fastest with alkenes?
Weakest H-X bond, easiest to break
Are atoms removed in addition reactions?
Are atoms removed in addition reactions?
No, all atoms add on
