Bond Energy (HSC SSCE Chemistry): Flashcards

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Bond Energy
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Bond energy

Energy needed to break a chemical bond

Symbol for bond energy

BB (e.g., BextCHB_{ ext{C-H}}, BextOHB_{ ext{O-H}})

Heat of atomisation

Enthalpy change to form gaseous atoms from element's std state

Symbol for heat of atomisation

ΔHat\Delta H_{\text{at}}^{\circ}

Bond energy & stability relationship

Higher bond energy = more stable, less reactive compound

Which bond determines molecular stability?

The weakest bond in the molecule

Formula: ΔH\Delta H^{\circ} from bond energies

ΔH\Delta H^{\circ} = (bonds broken) - (bonds formed)

Breaking bonds: energy required or released?

Requires energy (positive value)

Forming bonds: energy required or released?

Releases energy (negative value)

Accuracy of bond energy calculations

Not very accurate; bond energies are averages across compounds

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