Relating Properties, Uses, and Structure (HSC SSCE Chemistry): Flashcards

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Relating Properties, Uses, and Structure
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Properties of crystalline polymer regions

Rigid, high melting point, dense, opaque, impermeable

Properties of amorphous polymer regions

Flexible, low melting point, transparent, less dense, permeable

Effect of low branching on polymers

Higher crystallinity, density, strength; reduced transparency

Effect of longer polymer chains

Higher melting points and increased hardness

How larger side groups affect flexibility

Reduce flexibility, make polymer stiffer and more rigid

Cross-linking in polymers

Creates bonds between chains, forming rigid network structures

Vulcanisation process

Heating rubber with sulfur to form S-S bonds between chains

Why heavily cross-linked polymers can't be recycled

Covalent bonds don't break when heated; material decomposes

Bond types in most synthetic polymers

Strong covalent C-C and C-H bonds

How to increase polymer biodegradability

Copolymerisation with natural polymers like starch

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