Commercial Electrolytic Cells (VCE SSCE Chemistry): Flashcards

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Commercial Electrolytic Cells
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Energy conversion in commercial electrolytic cells

Electrical energy to chemical energy

Products of Downs cell

Sodium metal and chlorine gas

Electrolyte type in Downs cell

Molten sodium chloride

Why add CaCl2\text{CaCl}_2 to Downs cell?

Lowers melting point from 801°C801°\text{C} to ~600°C600°\text{C}

Three products of membrane cell

NaOH\text{NaOH} solution, Cl2\text{Cl}_2 gas, H2\text{H}_2 gas

What passes through membrane in membrane cell?

Only positive ions

Impurity percentage in blister copper

Approximately 2%2\%

Solvent for alumina in Hall-Héroult cell

Molten cryolite (Na3AlF6\text{Na}_3\text{AlF}_6)

Operating temperature of Hall-Héroult cell

950-1000°C950\text{-}1000°\text{C}

Nature of carbon anodes in Hall-Héroult cell

Reactive and consumed over time

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