Electrolytic Cells (VCE SSCE Chemistry): Flashcards

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Electrolytic Cells
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Electrolysis definition

Uses electrical energy to drive non-spontaneous reactions

Cathode charge & reaction type

Negative electrode; reduction (gain of electrons)

Anode charge & reaction type

Positive electrode; oxidation (loss of electrons)

Product at cathode in molten NaCl

Sodium metal (Na)

Product at anode in molten NaCl

Chlorine gas (Cl2\text{Cl}_2)

Which species reacts at cathode?

Strongest oxidising agent present

Which species reacts at anode?

Strongest reducing agent present

Energy conversion in electrolytic cells

Electrical energy to chemical energy

Why don't NO3\text{NO}_3^- & SO42\text{SO}_4^{2-} react at anode?

Already at maximum oxidation state, can't lose more electrons

Ions attracted to cathode

Cations (positive ions)

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