Effect of Changes of Conditions on Rate of Reaction (VCE SSCE Chemistry): Flashcards

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Effect of Changes of Conditions on Rate of Reaction
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Five factors affecting reaction rate

Surface area, concentration, pressure, temperature, catalyst

Requirements for successful collision

Energy Ea\geq E_a and correct orientation

Effect of increased concentration on rate

More particles per volume → more frequent collisions

Why only surface area matters for solids

Only surface particles can collide with other reactants

Effect of 10°C temp increase on rate

Rate approximately doubles (100% increase)

Main reason temp increases rate so much

More particles have energy Ea\geq E_a

Maxwell-Boltzmann distribution

Shows spread of kinetic energies amongst particles

M-B curve shape at higher temperature

Lower and broader peak

M-B curve peak position at higher temp

Shifts right (towards higher energies)

Total area under M-B curve with temp change

Stays constant (same number of particles)

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