Structure, Bonding & Reactivity (AQA A-Level Chemistry): Flashcards

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Structure, Bonding & Reactivity
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General formula of alkenes

CnH2nC_nH_{2n}

Why alkenes are unsaturated

Don't contain maximum number of H atoms

Two parts of C=CC=C double bond

Sigma (σσ) bond and pi (ππ) bond

How sigma bond forms in C=CC=C

Overlap of two sp² hybrid orbitals

How pi bond forms in C=CC=C

Side-to-side overlap of unhybridised p-orbitals

Bond angle around each C in C=CC=C

Approximately 120°

Why C=CC=C has restricted rotation

Due to presence of pi bond

Consequence of restricted rotation in alkenes

Geometrical isomerism (cis/trans or E/Z)

Why pi bond is more reactive than sigma

Pi bond is weaker than sigma bond

Main type of reactions alkenes undergo

Addition reactions (pi bond broken)

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