Oxidation of Alcohols (AQA A-Level Chemistry): Flashcards

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Oxidation of Alcohols
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Primary alcohol: carbons attached to −OH-OH carbon

One other carbon

Secondary alcohol: carbons attached to −OH-OH carbon

Two other carbons

Tertiary alcohol: carbons attached to −OH-OH carbon

Three other carbons

Partial oxidation product of primary alcohols

Aldehyde

Complete oxidation product of primary alcohols

Carboxylic acid

Colour change with acidified dichromate oxidation

Orange to green

Oxidation product of secondary alcohols

Ketones

Oxidation behaviour of tertiary alcohols

Resistant to oxidation/non-oxidisable

Fehling's test result for aldehydes

Blue solution to red precipitate (Cu2OCu_2O)

Tollens' test result for aldehydes

Silver mirror forms (Ag0Ag^0)

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