Mass spectrometry (AQA A-Level Chemistry): Flashcards

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Mass spectrometry
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Purpose of mass spectrometry

Determine molecular mass and formula of compounds

m/z in mass spectrometry

Mass-to-charge ratio

Ionisation in mass spectrometry

High-energy electrons create positive molecular ions

What deflects ions by their m/z ratio?

Magnetic field

Location of molecular ion peak (M+M^+)

Highest m/z value in spectrum

What molecular ion peak (M+M^+) indicates

MrM_r of whole molecule

What fragmentation peaks represent

Fragments of the original molecule

HRMS precision

Four decimal places

HRMS m/z: propane (C3H8C_3H_8) vs ethanal (CH3CHOCH_3CHO)

44.0624 vs 44.0302

First step to find molecular formula from mass spectrum

Locate M+M^+ peak, use precise m/z value

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