Mass spectrometry (AQA A-Level Chemistry): Quizzes

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Mass spectrometry
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What is mass spectrometry primarily used to determine?

Molecular mass and formula

What happens to a sample when it passes through a mass spectrometer?

It is ionised and fragmented

During ionisation, what bombardment causes the sample to form positive ions?

High-energy electrons

What deflects ions based on their m/zm/z ratio in a mass spectrometer?

A magnetic field

Where does the molecular ion peak (M+M^+) appear in a mass spectrum?

At the highest m/zm/z value

If the molecular ion peak appears at m/zm/z = 58, what is the MrM_r of the compound?

58

What do the fragmentation peaks in a mass spectrum represent?

Parts of the molecule

To how many decimal places can high-resolution mass spectrometry measure masses?

Four decimal places

What is the precise m/zm/z value for propane (C3H8C_3H_8) using HRMS?

44.0624

A fragment peak at m/zm/z = 29 may indicate the presence of which group?

Ethyl group (C2H5+C_2H_5^+)

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